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dc.contributor.authorGuilarte Moreno, Verónica 
dc.contributor.authorFernández Rodríguez, Manuel A. 
dc.contributor.authorGarcía García, Patricia
dc.contributor.authorHernando Santa Cruz, Elsa 
dc.contributor.authorSanz Díez, Roberto 
dc.date.accessioned2016-01-21T09:51:47Z
dc.date.available2016-01-21T09:51:47Z
dc.date.issued2011-09
dc.identifier.issn1523-7060
dc.identifier.urihttp://hdl.handle.net/10259/3909
dc.description.abstractAn efficient synthesis of thiophenes and benzo[b]thiophenes has been developed from easily available bromoenynes and o-alkynylbromobenzene derivatives. This novel one-pot procedure involves a Pd-catalyzed C–S bond formation using a hydrogen sulfide surrogate followed by a heterocyclization reaction. Moreover, in situ functionalization with selected electrophiles further expands the potential of this methodology to the preparation of the corresponding highly substituted sulfur heterocycles.en
dc.description.sponsorshipJunta de Castilla y Leon (BU021A09 and GR-172) and Ministerio de Ciencia e Innovacion (MICINN) and FEDER (CTQ2010-15358 and CTQ2009-09949/BQU) for financial support. P.G.-G. and M.A.F.-R. thank MICINN for "Juan de la Cierva" and "Ramon y Cajal" contractsen
dc.description.sponsorshipJunta de Castilla y Leon (BU021A09 and GR-172) and Ministerio de Ciencia e Innovacion (MICINN) and FEDER (CTQ2010-15358 and CTQ2009-09949/BQU) for financial support. P.G.-G. and M.A.F.-R. thank MICINN for "Juan de la Cierva" and "Ramon y Cajal" contracts
dc.format.mimetypeapplication/pdf
dc.language.isoenges
dc.publisherAmerican Chemical Societyen
dc.relation.ispartofOrganic Letters. 2011. V. 13, n. 19, p. 5100-5103en
dc.subject.otherQuímica orgánicaes
dc.subject.otherChemistry, Organicen
dc.titleA Practical, One-Pot Synthesis of Highly Substituted Thiophenes and Benzo[b]thiophenes from Bromoenynes and o-Alkynylbromobenzenesen
dc.typeArtículoes
dc.typeinfo:eu-repo/semantics/article
dc.description.versionThis document is the Accepted Manuscript version of a Published Work that appeared in final form in Organic Letters, copyright © American Chemical Society after peer review and technical editing by the publisher.
dc.rights.accessRightsinfo:eu-repo/semantics/openAccess
dc.relation.publisherversionhttp://dx.doi.org/10.1021/ol201970m
dc.identifier.doi10.1021/ol201970m
dc.subject.unescoChemistry, Organicen
dc.relation.projectIDinfo:eu-repo/grantAgreement/MICINN/CTQ2010-15358
dc.relation.projectIDinfo:eu-repo/grantAgreement/MICINN/CTQ2009-09949/BQU
dc.relation.projectIDinfo:eu-repo/grantAgreement/JCyL/BU021A09
dc.relation.projectIDinfo:eu-repo/grantAgreement/JCyL/GR-172
dc.type.hasVersioninfo:eu-repo/semantics/acceptedVersionen


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