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dc.contributor.authorRubio Martínez, Laura 
dc.contributor.authorSarabia Peinador, Luis Antonio 
dc.contributor.authorOrtiz Fernández, Mª Cruz 
dc.date.accessioned2016-10-19T07:17:02Z
dc.date.available2017-06-01T02:45:07Z
dc.date.issued2015-06
dc.identifier.issn0039-9140
dc.identifier.urihttp://hdl.handle.net/10259/4255
dc.description.abstractThe simultaneous determination of two carbamate pesticides (carbaryl and carbendazim) and of the degradation product of carbaryl (1-naphthol) in iceberg lettuce was achieved by means of PARAFAC decomposition and excitation–emission fluorescence matrices. A standard addition method for a calibration based on four-way data was applied using different dilutions of the extract from iceberg lettuce as a fourth way that provided the enough variation of the matrix to carry out the four-way analysis. A high fluorescent overlapping existed between the three analytes and the fluorophores of the matrix. The identification of two fluorescent matrix constituents through the four-way model enabled to know the matrix contribution in each dilution of the extract. This contribution was subtracted from the previous signals and a subsequent three-way analysis was carried out with the tensors corresponding to each dilution. The PARAFAC decomposition of these resulting tensors showed a CORCONDIA index equal to 99%. For the identification of the analytes, the correlation between the PARAFAC spectral loadings and the reference spectra has been used. The trueness of the method, in the concentration range studied, was guaranteed because there was neither constant nor proportional bias according to the appropriate hypothesis tests. The best recovery percentages were obtained with the data from the most diluted extract, being the results: 127.6% for carbaryl, 125.55% for carbendazim and 87.6% for 1-naphthol. When the solvent calibration was performed, the decision limit (CCα) and the capability of detection (CCβ) values, in x0=0, were 2.21 and 4.38 μg L−1 for carbaryl, 4.87 and 9.64 μg L−1 for carbendazim; and 3.22 and 6.38 μg L−1 for 1-naphthol, respectively, for probabilities of false positive and false negative fixed at 0.05. However, these values were 5.30 and 10.49 μg L−1 for carbaryl, 18.05 and 35.73 μg L−1 for carbendazim; and 1.92 and 3.79 μg L−1 for 1-naphthol, respectively, when the matrix-matched calibration using the most diluted extract was carried out in the recovery study.en
dc.description.sponsorshipMinisterio de Economía y Competitividad(CTQ2011-26022) and JuntadeCastillayLeón(BU108A11-2).en
dc.format.mimetypeapplication/pdf
dc.language.isoenges
dc.publisherElsevieren
dc.relation.ispartofTalanta. 2015, V. 138, p. 86–99en
dc.rightsAttribution-NonCommercial-NoDerivatives 4.0 International
dc.rights.urihttp://creativecommons.org/licenses/by-nc-nd/4.0/
dc.subjectCarbamate pesticidesen
dc.subjectExcitation–emission fluorescenceen
dc.subjectParallel factor analysisen
dc.subjectFour-way dataen
dc.subjectIceberg lettuceen
dc.subjectCapability of detectionen
dc.subject.otherQuímica analíticaes
dc.subject.otherChemistry, Analyticen
dc.titleStandard addition method based on four-way PARAFAC decomposition to solve the matrix interferences in the determination of carbamate pesticides in lettuce using excitation–emission fluorescence dataen
dc.typeArtículoes
dc.typeinfo:eu-repo/semantics/article
dc.rights.accessRightsinfo:eu-repo/semantics/openAccess
dc.relation.publisherversionhttp://dx.doi.org/10.1016/j.talanta.2015.01.042
dc.identifier.doi10.1016/j.talanta.2015.01.042
dc.relation.projectIDinfo:eu-repo/grantAgreement/MINECO/CTQ2011-26022
dc.relation.projectIDinfo:eu-repo/grantAgreement/JCyL/BU108A11-2
dc.type.hasVersioninfo:eu-repo/semantics/acceptedVersionen


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