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dc.contributor.authorVaquero Gutiérrez, Mónica 
dc.contributor.authorRuiz Riaguas, Alba
dc.contributor.authorMartínez Alonso, Marta
dc.contributor.authorJalón, Félix A. .
dc.contributor.authorManzano, Blanca R. .
dc.contributor.authorRodríguez, Ana M. .
dc.contributor.authorGarcía Herbosa, Gabriel 
dc.contributor.authorCarbayo Martín, Mª Aránzazu 
dc.contributor.authorGarcía Ruiz, Begoña 
dc.contributor.authorEspino Ordóñez, Gustavo 
dc.date.accessioned2018-08-27T08:18:09Z
dc.date.available2019-07-25T02:45:07Z
dc.date.issued2018-07
dc.identifier.issn0947-6539
dc.identifier.urihttp://hdl.handle.net/10259/4885
dc.description.abstractA new family of heteroleptic bis-cyclometalated IrIII complexes with formula [Ir(C _ N)2(N _ N)]Cl (C _ N=2-phenylpyridinate and N _ N=2,2’-dipyridylamine or N-benzylated 2,2’-dipyridylamines, were synthesized, characterized, and successfully used as photosensitizers in the catalytic photooxidation of an array of dialkyl, dibenzyl, alkyl aryl, and diaryl sulfides, as well as sulfur-containing amino acids. Furthermore, the reactions proceeded with optimal chemoselectivity, and atom economy under mild conditions. Experimental observations support a dual mechanism in which singlet oxygen and superoxide are the actual oxidants.en
dc.description.sponsorshipConsejer &a de Educacijn-Junta de Castilla y Lejn (BU042U16). Financial support by the Spanish Ministry of Economy and Competitiveness (MINECO) (projects CTQ2014-58812-C2@1-R, (CTQ2014-58812-C2-2-R, CTQ2015-70371-REDT, FEDER funds), Obra Social “la Caixa” (OSLC-2012-007), Junta de Castilla y Lejn (BU-042U16)en
dc.format.mimetypeapplication/pdf
dc.language.isoenges
dc.publisherWiley-VCH Verlagen
dc.relation.ispartofChemistry-a european journal. 2018, V. 24, n. 42, p. 10662-10671en
dc.subject.otherQuímicaes
dc.subject.otherChemistryen
dc.titleSelective photooxidation of sulfides catalyzed by bis‐cyclometalated IrIII photosensitizers bearing 2,2′‐dipyridylamine‐based ligandsen
dc.typeArtículoes
dc.typeinfo:eu-repo/semantics/article
dc.rights.accessRightsinfo:eu-repo/semantics/openAccess
dc.relation.publisherversionhttps://doi.org/10.1002/chem.201801173
dc.identifier.doi10.1002/chem.201801173
dc.relation.projectIDinfo:eu-repo/grantAgreement/JCyL/BU042U16
dc.relation.projectIDinfo:eu-repo/grantAgreement/MINECO/CTQ2014-58812-C2-1-R
dc.relation.projectIDinfo:eu-repo/grantAgreement/MINECO/CTQ2014-58812-C2-2-R
dc.relation.projectIDinfo:eu-repo/grantAgreement/MINECO/CTQ2015-70371-REDT
dc.relation.projectIDinfo:eu-repo/grantAgreement/FundaciónLaCaixa/OSLC-2012-007
dc.type.hasVersioninfo:eu-repo/semantics/acceptedVersionen


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