Show simple item record

dc.contributor.authorVirumbrales, Cintia 
dc.contributor.authorSuarez Pantiga, Samuel 
dc.contributor.authorSolas Luera, Marta 
dc.contributor.authorFernández Rodríguez, Manuel A. 
dc.contributor.authorSanz Díez, Roberto 
dc.date.accessioned2018-09-07T08:21:18Z
dc.date.available2019-04-21T02:45:07Z
dc.date.issued2018-04
dc.identifier.issn1477-0520
dc.identifier.urihttp://hdl.handle.net/10259/4920
dc.description.abstractThe gold(I)-catalyzed oxycyclization of β-aryl monosubstituted o-(alkynyl)styrenes gives rise to 1-α-methoxy or 1-α-hydroxybenzyl- 1H-indenes in a diastereospecific way. In contrast to β,β-disubstituted o-(alkynyl)styrenes, the stereochemical outcome of this process, diastereospecific reaction supports the higher contribution of a gold intermediate with a cyclopropylcarbene-like character.en
dc.description.sponsorshipMinisterio de Economía y Competitividad (MINECO) and FEDER (CTQ2016-75023-C2-1- P), and Junta de Castilla y León and FEDER (BU076U16)en
dc.format.mimetypeapplication/pdf
dc.language.isoenges
dc.publisherRoyal Society of Chemistryen
dc.relation.ispartofOrganic & Biomolecular Chemistry. 2018, V. 16, n. 15, p. 2623-2628en
dc.subject.otherQuímica orgánicaes
dc.subject.otherChemistry, Organicen
dc.titleGold(I)-catalyzed diastereoselective synthesis of 1-α-oxybenzyl-1H-indenesen
dc.typeArtículoes
dc.typeinfo:eu-repo/semantics/article
dc.rights.accessRightsinfo:eu-repo/semantics/openAccess
dc.relation.publisherversionhttps://doi.org/10.1039/c8ob00406d
dc.identifier.doi10.1039/c8ob00406d
dc.relation.projectIDinfo:eu-repo/grantAgreement/MINECO/CTQ2016-75023-C2-1-P
dc.relation.projectIDinfo:eu-repo/grantAgreement/JCyL/BU076U16
dc.type.hasVersioninfo:eu-repo/semantics/acceptedVersionen


Files in this item

Thumbnail

This item appears in the following Collection(s)

Show simple item record