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| dc.contributor.author | Virumbrales Ortiz, Cintia | |
| dc.contributor.author | Suárez Pantiga, Samuel | |
| dc.contributor.author | Solas Luera, Marta | |
| dc.contributor.author | Fernández Rodríguez, Manuel A. | |
| dc.contributor.author | Sanz Díez, Roberto | |
| dc.date.accessioned | 2018-09-07T08:21:18Z | |
| dc.date.available | 2019-04-21T02:45:07Z | |
| dc.date.issued | 2018-04 | |
| dc.identifier.issn | 1477-0520 | |
| dc.identifier.uri | http://hdl.handle.net/10259/4920 | |
| dc.description.abstract | The gold(I)-catalyzed oxycyclization of β-aryl monosubstituted o-(alkynyl)styrenes gives rise to 1-α-methoxy or 1-α-hydroxybenzyl- 1H-indenes in a diastereospecific way. In contrast to β,β-disubstituted o-(alkynyl)styrenes, the stereochemical outcome of this process, diastereospecific reaction supports the higher contribution of a gold intermediate with a cyclopropylcarbene-like character. | en |
| dc.description.sponsorship | Ministerio de Economía y Competitividad (MINECO) and FEDER (CTQ2016-75023-C2-1- P), and Junta de Castilla y León and FEDER (BU076U16) | en |
| dc.format.mimetype | application/pdf | |
| dc.language.iso | eng | es |
| dc.publisher | Royal Society of Chemistry | en |
| dc.relation.ispartof | Organic & Biomolecular Chemistry. 2018, V. 16, n. 15, p. 2623-2628 | en |
| dc.subject.other | Química orgánica | es |
| dc.subject.other | Chemistry, Organic | en |
| dc.title | Gold(I)-catalyzed diastereoselective synthesis of 1-α-oxybenzyl-1H-indenes | en |
| dc.type | info:eu-repo/semantics/article | |
| dc.rights.accessRights | info:eu-repo/semantics/openAccess | |
| dc.relation.publisherversion | https://doi.org/10.1039/c8ob00406d | |
| dc.identifier.doi | 10.1039/c8ob00406d | |
| dc.relation.projectID | info:eu-repo/grantAgreement/MINECO/CTQ2016-75023-C2-1-P | |
| dc.relation.projectID | info:eu-repo/grantAgreement/JCyL/BU076U16 | |
| dc.type.hasVersion | info:eu-repo/semantics/acceptedVersion | en |
