Dichlorodioxomolybdenum(VI) complexes: useful and readily available catalysts in organic synthesis

Hernández Ruiz, Raquel; Sanz Díez, Roberto

doi:10.1055/s-0037-1610236

Por favor, use este identificador para citar o enlazar este ítem: http://hdl.handle.net/10259/4922

Título

Dichlorodioxomolybdenum(VI) complexes: useful and readily available catalysts in organic synthesis

Autor

Hernández Ruiz, Raquel

Sanz Díez, Roberto

Publicado en

Synthesis. 2018, V. 50, n. 20, p. 4019-4036

Editorial

Thieme Publishing

Fecha de publicación

2018-10

ISSN

0039-7881

DOI

10.1055/s-0037-1610236

Abstract

Molybdenum(VI) dichloride dioxide (MoO2Cl2), and its addition complexes [MoO2Cl2(L)n; L = neutral ligand], are commercially or easily available and inexpensive transition-metal complexes based on a non-noble metal that can be applied as catalysts for various organic transformations. This short review aims to present the most significant breakthroughs in this field.

Palabras clave

dioxomolybdenum(VI) complexes

reduction

oxidation

deoxygenation

Lewis acid

nitroaromatics

Materia

Química orgánica

Chemistry, Organic

URI

http://hdl.handle.net/10259/4922