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| dc.contributor.author | Feberero García, Claudia | |
| dc.contributor.author | Suarez Pantiga, Samuel | |
| dc.contributor.author | Cabello Fernández, Zaida | |
| dc.contributor.author | Sanz Díez, Roberto | |
| dc.date.accessioned | 2018-09-07T10:42:31Z | |
| dc.date.available | 2019-04-20T02:45:07Z | |
| dc.date.issued | 2018-04 | |
| dc.identifier.issn | 1523-7060 | |
| dc.identifier.uri | http://hdl.handle.net/10259/4925 | |
| dc.description.abstract | The reaction of o-lithiated O-aryl N,N-diethylcarbamates with (hetero)aromatic nitriles gives rise to functionalized salicylidene urea derivatives in high yields through a new 1,5-O → N carbamoyl migration. This Snieckus–Fries-type rearrangement nicely complements previously known O → C and O → O related shifts. In addition, when dimethylmalononitrile is used as the electrophilic partner, the carbamoyl shift is preferred over the expected transnitrilation reaction. | en |
| dc.description.sponsorship | Junta de Castilla y León and FEDER (BU076U16) and Ministerio de Economía y Competitividad (MINECO) and FEDER (CTQ2016-48937-C2-1-P) | en |
| dc.format.mimetype | application/pdf | |
| dc.language.iso | eng | es |
| dc.publisher | American Chemical Society | en |
| dc.relation.ispartof | Organic Letters. 2018, V. 20, n. 8, p. 2437–2440 | en |
| dc.subject.other | Química orgánica | es |
| dc.subject.other | Chemistry, Organic | en |
| dc.title | 1,5-O → N Carbamoyl Snieckus–Fries-Type Rearrangement | en |
| dc.type | info:eu-repo/semantics/article | |
| dc.rights.accessRights | info:eu-repo/semantics/openAccess | |
| dc.relation.publisherversion | https://doi.org/10.1021/acs.orglett.8b00782 | |
| dc.identifier.doi | 10.1021/acs.orglett.8b00782 | |
| dc.relation.projectID | info:eu-repo/grantAgreement/JCyL/BU076U16 | |
| dc.relation.projectID | info:eu-repo/grantAgreement/MINECO/CTQ2016-48937-C2-1-P | |
| dc.type.hasVersion | info:eu-repo/semantics/acceptedVersion | en |
