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    Por favor, use este identificador para citar o enlazar este ítem: http://hdl.handle.net/10259/6181

    Título
    Insights on the water effect on deep eutectic solvents properties and structuring: The archetypical case of choline chloride + ethylene glycol
    Autor
    Rozas Azcona, Sara
    Benito, Cristina
    Alcalde García, Rafael T.UBU authority
    Atilhan, Mert .
    Aparicio Martínez, SantiagoUBU authority
    Publicado en
    Journal of Molecular Liquids. 2021, V. 344, 117717
    Editorial
    Elsevier
    Fecha de publicación
    2021-12
    ISSN
    0167-7322
    DOI
    10.1016/j.molliq.2021.117717
    Abstract
    The effect of water on the properties and nanostructuring of the prototypical choline chloride: ethylene glycol deep eutectic solvent is studied using a combined experimental and theoretical approach. The reported results showed large hydrophilic character of the solvent, which is based on the ability of water molecules to be hydrogen bonded to the different components of the eutectic in a efficient way. The effect of water on the studied fluid is largely dependent on the concentration range but the properties of the eutectic solvent can be maintained up to reasonably large water content. Therefore, the water content in these solvents may be used for tuning and controlling their properties but maintaining properties and features.
    Palabras clave
    Deep eutectic solvents
    Water
    Molecular modelling
    Physicochemical properties
    Intermolecular forces
    Water content
    Materia
    Química física
    Chemistry, Physical and theoretical
    URI
    http://hdl.handle.net/10259/6181
    Versión del editor
    https://doi.org/10.1016/j.molliq.2021.117717
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    Attribution-NonCommercial-NoDerivatives 4.0 Internacional
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