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    Por favor, use este identificador para citar o enlazar este ítem: http://hdl.handle.net/10259/6806

    Título
    Deoxygenation reactions in organic synthesis catalyzed by dioxomolybdenum(vi) complexes
    Autor
    Suarez Pantiga, SamuelUBU authority Orcid
    Sanz Díez, RobertoUBU authority Orcid
    Publicado en
    Organic & Biomolecular Chemistry. 2021, V. 19, n. 48, p. 10463-10670
    Editorial
    Royal Society of Chemistry
    Fecha de publicación
    2021-12
    ISSN
    1477-0520
    DOI
    10.1039/D1OB01939B
    Abstract
    Dioxomolybdenum(VI) complexes have been applied as efficient, inexpensive and benign catalysts to deoxygenation reactions of a diverse number of compounds in the last two decades. Dioxomolybdenum complexes have demonstrated wide applicability to the deoxygenation of sulfoxides into sulfides and reduction of N–O bonds. Even the challenging nitro functional group was efficiently deoxygenated, affording amines or diverse heterocycles after reductive cyclization reactions. More recently, carbon-based substrates like epoxides, alcohols and ketones have been successfully deoxygenated. Also, dioxomolybdenum complexes accomplished deoxydehydration (DODH) reactions of biomass-derived vicinal 1,2-diols, affording valuable alkenes. The choice of the catalytic systems and reductant is decisive to achieve the desired transformation. Commonly found reducing agents involved phosphorous-based compounds, silanes, molecular hydrogen, or even glycols and other alcohols.
    Materia
    Química orgánica
    Chemistry, Organic
    URI
    http://hdl.handle.net/10259/6806
    Versión del editor
    https://doi.org/10.1039/D1OB01939B
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    • Artículos SINTORG
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