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| dc.contributor.author | Velasco Pérez, Noelia | |
| dc.contributor.author | Martínez Núñez, Clara | |
| dc.contributor.author | Fernández Rodríguez, Manuel A. | |
| dc.contributor.author | Sanz Díez, Roberto | |
| dc.contributor.author | Suarez Pantiga, Samuel | |
| dc.date.accessioned | 2023-02-07T12:10:37Z | |
| dc.date.available | 2023-02-07T12:10:37Z | |
| dc.date.issued | 2022-07 | |
| dc.identifier.issn | 1615-4150 | |
| dc.identifier.uri | http://hdl.handle.net/10259/7413 | |
| dc.description.abstract | A tandem 1,3-sulfur migration followed by iodocyclization reaction of propargylic sulfides in the presence of NIS in HFIP has been developed to synthesize indene-based β-iodoalkenyl sulfides. The choice of the reaction media is crucial to promote the reaction. The proposed mechanism involving the initial NIS activation by HFIP and favoring the sulfur migration of the starting propargylic thioether via cationic intermediates is experimentally supported. In addition, the suitability of selected indene-based β-iodoalkenyl sulfides as building blocks for subsequent C C bond-forming reactions has been demonstrated. | en |
| dc.description.sponsorship | We gratefully acknowledge MICINN (PID2020-115789GBC21); and “NextGenerationEU/PRTR” (PDC2021-120825- C21), and Junta de Castilla y León and FEDER (BU049P20) for financial support. The project leading to these results has also received funding from “la Caixa” Foundation, under the Agreement LCF/PR/PR18/51130007> (CAIXA-UBU001). N.V. and S.S.-P. thank Junta de Castilla y León (Consejería de Educación) and Fondo Social Europeo for predoctoral (N.V) and postdoctoral (S.S.-P.) contracts, respectively. | en |
| dc.format.mimetype | application/pdf | |
| dc.language.iso | eng | es |
| dc.publisher | Wiley | en |
| dc.relation.ispartof | Advanced Synthesis & Catalysis. 2022, V. 364, n. 17, p. 2932-2938 | es |
| dc.rights | Atribución-NoComercial 4.0 Internacional | * |
| dc.rights.uri | http://creativecommons.org/licenses/by-nc/4.0/ | * |
| dc.subject | Synthetic methods | en |
| dc.subject | Sulfur | en |
| dc.subject | Alkenes | en |
| dc.subject | Alkynes | en |
| dc.subject | Halogens | en |
| dc.subject.other | Química orgánica | es |
| dc.subject.other | Chemistry, Organic | en |
| dc.title | NIS/HFIP‐Mediated Synthesis of Indene‐Based β‐Iodoalkenyl Sulfides from Propargylic Sulfides | en |
| dc.type | info:eu-repo/semantics/article | es |
| dc.rights.accessRights | info:eu-repo/semantics/openAccess | es |
| dc.relation.publisherversion | https://doi.org/10.1002/adsc.202200613 | es |
| dc.identifier.doi | 10.1002/adsc.202200613 | |
| dc.relation.projectID | info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2017-2020/PID2020-115789GB-C21/ES/ESTRATEGIAS SINTETICAS SOSTENIBLES PARA LA TRANSFORMACION DIRECTA DE NITROCOMPUESTOS Y DESARROLLO DE NUEVAS REACCIONES CATALIZADAS POR ORO/ | es |
| dc.relation.projectID | info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2017-2020/PDC2021-120825-C21/ES/Valorización de productos de la biomasa por catálisis con complejos de dioxomolibdeno/ | es |
| dc.relation.projectID | info:eu-repo/grantAgreement/Junta de Castilla y León//BU049P20//Estrategias sintéticas sostenibles para la halogenación directa de nitrocompuestos y la preparación de electrolitos orgánicos para baterías de flujo redox/ | es |
| dc.relation.projectID | info:eu-repo/grantAgreement/Fundación Bancaria Caixa d'Estalvis i Pensions de Barcelona//LCF%2FPR%2FPR18%2F51130007// Fluoración Directa de Nitrocompuestos y Sales de Heteroaril Fosfonio: Síntesis de Fluorocompuestos/FluNitroPhos/ | es |
| dc.identifier.essn | 1615-4169 | |
| dc.journal.title | Advanced Synthesis & Catalysis | en |
| dc.volume.number | 364 | es |
| dc.issue.number | 17 | es |
| dc.page.initial | 2932 | es |
| dc.page.final | 2938 | es |
| dc.type.hasVersion | info:eu-repo/semantics/publishedVersion | es |
