Synthesis of 1,4-ketoaldehydes and 1,4-diketones by Mo-catalyzed oxidative cleavage of cyclobutane-1,2-diols

Gómez Gil, Sara; Rubio Presa, Rubén; Hernández Ruiz, Raquel; Suárez Pantiga, Samuel; Pedrosa Sáez, María de los Remedios; Sanz Díez, Roberto

doi:10.1039/D3OB00436H

dc.contributor.author	Gómez Gil, Sara
dc.contributor.author	Rubio Presa, Rubén
dc.contributor.author	Hernández Ruiz, Raquel
dc.contributor.author	Suárez Pantiga, Samuel
dc.contributor.author	Pedrosa Sáez, María de los Remedios
dc.contributor.author	Sanz Díez, Roberto
dc.date.accessioned	2024-07-01T06:55:22Z
dc.date.available	2024-07-01T06:55:22Z
dc.date.issued	2023-04-26
dc.identifier.issn	1477-0520
dc.identifier.uri	http://hdl.handle.net/10259/9324
dc.description.abstract	A new two-step procedure for the synthesis of 1,4-dicarbonyls has been developed involving an efficient and clean Mo-catalyzed oxidative cleavage of cyclobutane-1,2-diols with DMSO, which is used as solvent and oxidant. The required starting glycols were prepared by nucleophilic additions of organolithiums and Grignard reagents to easily available 2-hydroxycyclobutanones.	en
dc.description.sponsorship	We gratefully acknowledge Ministerio de Ciencia e Innovación and FEDER (PID2020-115789GB-C21), and Junta de Castilla y León and FEDER (BU049P20) for financial support. S. G.-G. and R. H.-R. thank Ministerio de Educación for FPU predoctoral contracts. S. S.-P. thanks Ministerio de Ciencia e Innovación and “NextGenerationEU”/PRTR EU for a Ramón y Cajal contract (RYC2021-031533-I).	en
dc.format.mimetype	application/pdf
dc.language.iso	eng	es
dc.publisher	Royal Society of Chemistry	en
dc.relation.ispartof	Organic & Biomolecular Chemistry. 2023, V. 21, n. 20, p. 4185-4190	en
dc.rights	Atribución-NoComercial 4.0 Internacional	*
dc.rights.uri	http://creativecommons.org/licenses/by-nc/4.0/	*
dc.subject.other	Química orgánica	es
dc.subject.other	Chemistry, Organic	en
dc.subject.other	Biología molecular	es
dc.subject.other	Molecular biology	en
dc.title	Synthesis of 1,4-ketoaldehydes and 1,4-diketones by Mo-catalyzed oxidative cleavage of cyclobutane-1,2-diols	en
dc.type	info:eu-repo/semantics/article	es
dc.rights.accessRights	info:eu-repo/semantics/openAccess	es
dc.relation.publisherversion	https://doi.org/10.1039/D3OB00436H	es
dc.identifier.doi	10.1039/D3OB00436H
dc.identifier.essn	1477-0539
dc.journal.title	Organic & Biomolecular Chemistry	en
dc.volume.number	21	es
dc.issue.number	20	es
dc.page.initial	4185	es
dc.page.final	4190	es
dc.type.hasVersion	info:eu-repo/semantics/publishedVersion	es

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