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| dc.contributor.author | Martínez Núñez, Clara | |
| dc.contributor.author | Velasco Pérez, Noelia | |
| dc.contributor.author | Sanz Díez, Roberto | |
| dc.contributor.author | Suárez Pantiga, Samuel | |
| dc.date.accessioned | 2025-05-27T11:09:10Z | |
| dc.date.available | 2025-05-27T11:09:10Z | |
| dc.date.issued | 2024-01 | |
| dc.identifier.issn | 1359-7345 | |
| dc.identifier.uri | http://hdl.handle.net/10259/10499 | |
| dc.description.abstract | Conjugated 1-bromo or 1-iodo-1,3-dienes bearing a sulfide substituent have been synthesized via 1,2-sulfur migration from propargylic thioethers upon activation with NIS or NBS. The reaction generally proceeds with high control over the regio- and diastereoselectivity. Highly substituted thiophenes and selenophenes are easily obtained from the generated dienes. | en |
| dc.description.sponsorship | We gratefully acknowledge MCIN (PID2020-115789GB-C21/ AEI/10.13039/501100011033), and Junta de Castilla y Leo ´n and FEDER (BU028P23) for financial support. C. M.-N. thanks Junta de Castilla y Leo´n and Fondo Social Europeo, for a predoctoral contract. S. S.-P. thanks a Ramo ´n y Cajal (RYC2021-031533-I) contract by MCIN/AEI/10.13039/501100011033 and European Union ‘‘NextGenerationEU’’/PRTR. | en |
| dc.format.mimetype | application/pdf | |
| dc.language.iso | eng | es |
| dc.publisher | Royal Society of Chemistry | es |
| dc.relation.ispartof | Chemical Communications. 2024, V. 60, n. 13, p. 1794-1797 | es |
| dc.rights | Atribución 4.0 Internacional | * |
| dc.rights.uri | http://creativecommons.org/licenses/by/4.0/ | * |
| dc.subject.other | Química | es |
| dc.subject.other | Chemistry | en |
| dc.subject.other | Química orgánica | es |
| dc.subject.other | Chemistry, Organic | en |
| dc.title | Synthesis of highly substituted 1,3-dienes through halonium promoted 1,2-sulfur migration of propargylic thioethers | en |
| dc.type | info:eu-repo/semantics/article | es |
| dc.rights.accessRights | info:eu-repo/semantics/openAccess | es |
| dc.relation.publisherversion | https://doi.org/10.1039/D3CC06194A | es |
| dc.identifier.doi | 10.1039/D3CC06194A | |
| dc.identifier.essn | 1364-548X | |
| dc.journal.title | Chemical Communications | es |
| dc.volume.number | 60 | es |
| dc.issue.number | 13 | es |
| dc.page.initial | 1794 | es |
| dc.page.final | 1797 | es |
| dc.type.hasVersion | info:eu-repo/semantics/publishedVersion | es |
