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dc.contributor.authorTrigo López, Miriam 
dc.contributor.authorMuñoz Santamaría, María Asunción 
dc.contributor.authorIbeas Cortes, Saturnino 
dc.contributor.authorSerna Arenas, Felipe 
dc.contributor.authorGarcía García, Félix Clemente 
dc.contributor.authorGarcía Pérez, José Miguel 
dc.date.accessioned2017-01-30T09:56:47Z
dc.date.available2018-04-01T02:45:06Z
dc.date.issued2016-04
dc.identifier.urihttp://hdl.handle.net/10259/4315
dc.description.abstractColorimetric cation responsive water soluble polymers and manageable films or membranes have beendesigned. The sensory materials respond with a colour change to the presence in water of Fe(III), Co(II),Cu(II), and Sn(II). The colour change is specific of each metal cation, and enables its identification (purplefor iron, orange for cobalt, green for copper, and yellow for tin). The design of the materials relies onan addition monomer having a terpyridine moiety, which behaves as a dye in presence of transitionmetal cations due to its proven chelating capability towards these species and the colour developmentthat always accompany the metallic complex formation. Water solutions of the sensory linear polymersallow for the UV/vis titration of Fe(III), Co(II), Cu(II), and Sn(II) with a limit of detection of 1.3 × 10−7,6.4 × 10−8, 1.3 × 10−5and 1.4 × 10−5M, respectively. On the other hand, sensory kits, cut from sensorymembranes, permitted the visual quantification of the cations in a dynamic range of five decades (1 × 10−7to 5 × 10−3M) for Fe(III) and Co(II) and of two decades (9 × 10−5to 9 × 10−3M) for Cu(II) and Sn(II).Titration curves can also be drawn from a picture taken to the sensory kits with a smartphone, by usingthe digital colour definition of the materials as analytical signal. Also, after entering into contact withhands, shapes of metallic objects (iron and cobalt containing tools) can be colour revealed by pressingthe hands on paper or cotton fabrics wetted with water solutions of the linear sensory polymer.en
dc.description.sponsorshipSpanish Ministerio deEconomía y Competitividad-Feder (MAT2014-54137-R)en
dc.format.mimetypeapplication/pdf
dc.language.isoenges
dc.publisherElsevieren
dc.relation.ispartofSensors and Actuators B: Chemical. 2016, V. 226, p. 118–126en
dc.rightsAttribution-NonCommercial-NoDerivatives 4.0 International
dc.rights.urihttp://creativecommons.org/licenses/by-nc-nd/4.0/
dc.subjectSensory polymersen
dc.subjectTerpyridineen
dc.subjectCation detectionen
dc.subjectForensic applicationsaen
dc.subject.otherChemistryen
dc.subject.otherQuímicaes
dc.titleColorimetric detection and determination of Fe(III), Co(II), Cu(II) and Sn(II) in aqueous media by acrylic polymers with pendant terpyridine motifsen
dc.typeinfo:eu-repo/semantics/article
dc.rights.accessRightsinfo:eu-repo/semantics/openAccess
dc.relation.publisherversionhttp://dx.doi.org/10.1016/j.snb.2015.11.116
dc.type.hasVersioninfo:eu-repo/semantics/acceptedVersionen


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