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dc.contributor.authorVelasco Pérez, Noelia 
dc.contributor.authorVirumbrales, Cintia 
dc.contributor.authorSanz Díez, Roberto 
dc.contributor.authorSuarez Pantiga, Samuel 
dc.contributor.authorFernández Rodríguez, Manuel A. 
dc.date.accessioned2018-09-07T09:53:26Z
dc.date.available2019-05-18T02:45:07Z
dc.date.issued2018-05
dc.identifier.issn1523-7060
dc.identifier.urihttp://hdl.handle.net/10259/4923
dc.description.abstractThe cross-coupling reaction of alkenyl bromides with thiols catalyzed by palladium complexes derived from inexpensive dppf ligand is reported. These reactions occur under low catalyst loading and in high yields and display wide scope, including the coupling of bulky thiols and trisubstituted bromoolefins, and functional group tolerance. In addition, the thioetherification of less reactive chloroalkenes and, for the first time, alkenyl tosylates was accomplished using a catalyst generated from CyPFtBu alkylbisphosphine ligand.en
dc.description.sponsorshipJunta de Castilla y León and FEDER (BU076U16) and Ministerio de Economía y Competitividad (MINECO) and FEDER (CTQ2016-75023-C2-1-P)en
dc.format.mimetypeapplication/pdf
dc.language.isoenges
dc.publisherAmerican Chemical Societyen
dc.relation.ispartofOrganic Letters. 2018, V. 20, n. 10, p. 2848-2852en
dc.subject.otherQuímica orgánicaes
dc.subject.otherChemistry, Organicen
dc.titleGeneral synthesis of alkenyl sulfides by palladium-catalyzed thioetherification of alkenyl halides and tosylatesen
dc.typeArtículoes
dc.typeinfo:eu-repo/semantics/article
dc.rights.accessRightsinfo:eu-repo/semantics/openAccess
dc.relation.publisherversionhttps://doi.org/10.1021/acs.orglett.8b00854
dc.identifier.doi10.1021/acs.orglett.8b00854
dc.relation.projectIDinfo:eu-repo/grantAgreement/JCyL/BU076U16
dc.relation.projectIDinfo:eu-repo/grantAgreement/MINECO/CTQ2016-75023-C2-1-P
dc.type.hasVersioninfo:eu-repo/semantics/acceptedVersionen


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