Mostrar el registro sencillo del ítem
| dc.contributor.author | Cabrera Lobera, Natalia | |
| dc.contributor.author | Velasco Pérez, Noelia | |
| dc.contributor.author | Sanz Díez, Roberto | |
| dc.contributor.author | Fernández Rodríguez, Manuel A. | |
| dc.date.accessioned | 2019-11-13T08:45:15Z | |
| dc.date.available | 2019-11-13T08:45:15Z | |
| dc.date.issued | 2019-08 | |
| dc.identifier.issn | 0040-4020 | |
| dc.identifier.uri | http://hdl.handle.net/10259/5177 | |
| dc.description.abstract | A practical and environmentally benign Brønsted acid−catalyzed protocol for the preparation of all-carbon tetrasubstituted allenes, consisting in the direct SNˈ addition of tri- or dimethoxy arenes or allyltrimethylsilane to tertiary propargylic alcohols, has been developed. In addition, a straightforward synthesis of densely substituted 2H-chromenes by metal-free tandem allenylation/heterocyclization reaction of methoxyphenols and tertiary alkynols is presented. | en |
| dc.description.sponsorship | Junta de Castilla y León and FEDER (BU291P18) and Ministerio de Economía y Competitividad (MINECO) and FEDER (CTQ2016-75023-C2-1-P) | |
| dc.format.mimetype | application/pdf | |
| dc.language.iso | eng | |
| dc.publisher | Elsevier | |
| dc.relation.ispartof | Tetrahedron. 2019, V. 75, n. 31, p. 4071-4080 | |
| dc.rights.uri | http://creativecommons.org/licenses/by-nc-nd/4.0/ | * |
| dc.subject | Allenes | en |
| dc.subject | Brønsted acid catalysis | en |
| dc.subject | Propargylic alcohols | en |
| dc.subject | 2H-chromenes | en |
| dc.subject | Nucleophilic substitution | en |
| dc.subject.other | Química orgánica | es |
| dc.subject.other | Chemistry, Organic | en |
| dc.title | Brønsted acid−catalyzed synthesis of tetrasubstituted allenes and polysubstituted 2H-chromenes from tertiary propargylic alcohols | en |
| dc.type | info:eu-repo/semantics/article | |
| dc.rights.holder | Attribution-NonCommercial-NoDerivatives 4.0 Internacional | * |
| dc.rights.accessRights | info:eu-repo/semantics/openAccess | |
| dc.relation.publisherversion | https://doi.org/10.1016/j.tet.2019.05.023 | |
| dc.identifier.doi | 10.1016/j.tet.2019.05.023 | |
| dc.identifier.doi | 10.1016/j.tet.2019.05.023 | |
| dc.relation.projectID | info:eu-repo/grantAgreement/JCyL/BU291P18 | |
| dc.relation.projectID | info:eu-repo/grantAgreement/MINECO/CTQ2016-75023-C2-1-P | |
| dc.type.hasVersion | info:eu-repo/semantics/acceptedVersion |
