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| dc.contributor.author | Virumbrales Ortiz, Cintia | |
| dc.contributor.author | Solas Luera, Marta | |
| dc.contributor.author | Suárez Pantiga, Samuel | |
| dc.contributor.author | Fernández Rodríguez, Manuel A. | |
| dc.contributor.author | Marín Luna, Marta | |
| dc.contributor.author | Silva López, Carlos | |
| dc.contributor.author | Sanz Díez, Roberto | |
| dc.date.accessioned | 2020-01-23T12:46:56Z | |
| dc.date.available | 2020-01-23T12:46:56Z | |
| dc.date.issued | 2019-12 | |
| dc.identifier.issn | 1477-0520 | |
| dc.identifier.uri | http://hdl.handle.net/10259/5213 | |
| dc.description.abstract | The stereospecific gold(I)-catalyzed nucleophilic cyclization of β-monosubstituted o-(alkynyl)styrenes to produce C-1 functionalized 1H-indenes including challenging substrates and nucleophiles, such as β-(cyclo)alkyl-substituted o-(alkynyl)styrenes and a variety of alcohols as well as selected electron-rich aromatics, is reported. DFT calculations support the stereochemical outcome of the process that involves the formation of a key cyclopropyl gold carbene intermediate through a regiospecific 5-endo cyclization. | en |
| dc.description.sponsorship | Ministerio de Economía y Competitividad (MINECO) and FEDER (CTQ2016-75023-C2-1-P and 2-P), and Junta de Castilla y León and FEDER (BU291P18) and Xunta de Galicia (ED431C 2017/70 and ED431E 2018/07) | es |
| dc.format.mimetype | application/pdf | |
| dc.language.iso | eng | |
| dc.publisher | Royal Society of Chemistry | |
| dc.relation.ispartof | Organic & Biomolecular Chemistry. 2019, V. 17, n. 46, p. 9924-9932 | |
| dc.subject.other | Química orgánica | es |
| dc.subject.other | Chemistry, Organic | en |
| dc.title | Gold(i)-catalyzed nucleophilic cyclization of β-monosubstituted o-(alkynyl)styrenes: a combined experimental and computational study | en |
| dc.type | info:eu-repo/semantics/article | |
| dc.rights.accessRights | info:eu-repo/semantics/openAccess | |
| dc.relation.publisherversion | https://doi.org/10.1039/C9OB02126D | |
| dc.identifier.doi | 10.1039/C9OB02126D | |
| dc.relation.projectID | info:eu-repo/grantAgreement/MINECO/CTQ2016-75023-C2-1-P | |
| dc.relation.projectID | info:eu-repo/grantAgreement/MINECO/CTQ2016-75023-C2-2-P | |
| dc.relation.projectID | info:eu-repo/grantAgreement/JCyL/BU291P18 | |
| dc.relation.projectID | info:eu-repo/grantAgreement/XG/ED431C 2017/70 | |
| dc.relation.projectID | info:eu-repo/grantAgreement/XG/ED431E 2018/07) | |
| dc.identifier.essn | 1477-0539 | |
| dc.type.hasVersion | info:eu-repo/semantics/acceptedVersion |
