Por favor, use este identificador para citar o enlazar este ítem: http://hdl.handle.net/10259/6179
A combined experimental and theoretical study on diglyme + 1-alkanol liquid mixtures
Journal of Molecular Liquids. 2021, V. 334, 116048
Fecha de publicación
The properties, structuring and intermolecular forces of diglyme + alkanol mixtures are studied using a combined experimental and theoretical approach. The thermophysical properties as well as the molecular simulation results provide detailed characterization of the mixtures in terms of composition, type of 1-alkanol and temperature. The possibility of development of heteroassociations by glyme - alkanol hydrogen bonding as well as their effect on the weakening and breaking on alkanols self-association show a pivotal role on the mixtures structure as well as the glyme self-association. The reported mixtures show complex structural effects varying with mixtures composition which may be considered as model of ether – hydroxyl interaction and their effects on the mixture’s properties and nature.
Chemistry, Physical and theoretical
Versión del editor
Documento(s) sujeto(s) a una licencia Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 Internacional