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dc.contributor.authorUtzeri, Gianluca
dc.contributor.authorGuirado Moreno, José Carlos 
dc.contributor.authorCova, Tânia Firmino Guerra Guerreiro da
dc.contributor.authorPais, Alberto A. C. C.
dc.contributor.authorCarvalho, Luís A. E. Batista de
dc.contributor.authorIbeas Cortes, Saturnino 
dc.contributor.authorGarcía Pérez, José Miguel 
dc.contributor.authorValente, Artur J. M.
dc.contributor.authorVallejos Calzada, Saúl 
dc.date.accessioned2024-05-25T15:14:21Z
dc.date.available2024-05-25T15:14:21Z
dc.date.issued2024-05-14
dc.identifier.urihttp://hdl.handle.net/10259/9179
dc.description.abstractThis study introduces reusable polyacrylic membranes, fabricated from commercially available monomers (1-vinyl-2-pyrrolidone and methylmethacrylate), as a promising approach for pesticide extraction. These membranes effectively remove the commonly used herbicides mecoprop (RE ≈ 99%) and bentazon (RE ≈ 95%) at low concentrations, which pose water contamination risks due to their water-soluble properties and leaf-level sorption. The membranes exhibit excellent manageability and resistance, allowing for safe handling without personal protective equipment. Additionally, the material is environmentally friendly and can be washed and reused for at least 4 cycles without a significant decrease in performance. Characterization techniques, including NMR, TGA, DSC, mechanical testing, N2 adsorption, and FTIR analysis, were used to investigate properties and assess the influence of the polymeric composition. The study focused on examining the lateral charged aminoethyl groups, which play a crucial role in sorbent-sorbate interactions. Sorption kinetics, isotherms, and permeation studies provided insights into the removal mechanism, efficiency, and permeability coefficients, revealing hydrophobic–hydrophobic interactions between the pesticides and the polymer. Molecular dynamics simulations revealed a scorpion-like conformation of the macromolecular chains surrounding the pesticides. These findings support the hydrophobic nature of the extraction mechanism and highlight the significant role of charged aminoethyl groups in facilitating this process.en
dc.description.sponsorshipWe gratefully acknowledge the financial support provided by all funders. The financial support provided by Fondo Europeo de Desarrollo Regional-European Regional Development Fund (FEDER, ERDF) and Regional Government of Castilla y León -Consejería de Educación, Junta de Castilla y León- (BU025P23) is gratefully acknowledged. This work was supported by the Regional Government of Castilla y León (Junta de Castilla y León) and by the Ministry of Science and Innovation MICIN and the European Union NextGenerationEU PRTR. J.M.G. received grant PID2020-113264RB-I00 funded by MCIN/AEI/ 10.13039/501100011033 and by “ERDF A way of making Europe”. S.V. received grant BG22/00086 funded by Spanish Ministerio de Universidades. The authors also acknowledge Fundação para a Ciência e a Tecnologia (FCT), the Portuguese Agency for Scientific Research for the financial support through project UIDP/00313/2020. T.C. acknowledges the Junior Researcher Grant CEECIND/00915/2018 assigned by FCT. G.U. thanks FCT for the PhD grant SFR/BD/146358/2019.en
dc.format.mimetypeapplication/pdf
dc.language.isoenges
dc.publisherSpringer Natureen
dc.relation.ispartofnpj Clean Water. 2024, V. 7, n. 1en
dc.rightsAtribución 4.0 Internacional*
dc.rights.urihttp://creativecommons.org/licenses/by/4.0/*
dc.subject.otherQuímica orgánicaes
dc.subject.otherChemistry, Organicen
dc.subject.otherPolímeroses
dc.subject.otherPolymersen
dc.titleReusable and effective polyacrylic membranes for mecoprop and bentazon extractionsen
dc.typeinfo:eu-repo/semantics/articlees
dc.rights.accessRightsinfo:eu-repo/semantics/openAccesses
dc.relation.publisherversionhttps://doi.org/10.1038/s41545-024-00328-3es
dc.identifier.doi10.1038/s41545-024-00328-3
dc.identifier.essn2059-7037
dc.journal.titlenpj Clean Wateren
dc.volume.number7es
dc.issue.number1es
dc.type.hasVersioninfo:eu-repo/semantics/publishedVersiones


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