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| dc.contributor.author | Álvarez Manuel, Estela | |
| dc.contributor.author | Miguel, Delia | |
| dc.contributor.author | García García, Patricia | |
| dc.contributor.author | Fernández Rodríguez, Manuel A. | |
| dc.contributor.author | Rodríguez, Félix | |
| dc.contributor.author | Sanz Díez, Roberto | |
| dc.date.accessioned | 2015-07-27T09:55:12Z | |
| dc.date.available | 2015-07-27T09:55:12Z | |
| dc.date.issued | 2011-06 | |
| dc.identifier.issn | 1860-5397 | |
| dc.identifier.uri | http://hdl.handle.net/10259/3799 | |
| dc.description.abstract | The selectivity of our previously described gold-catalyzed tandem reaction, 1,2-indole migration followed by aura-iso-Nazarov cyclization, of 3-propargylindoles bearing (hetero)aromatic substituents at both the propargylic and terminal positions, was reversed by the proper choice of the catalyst and the reaction conditions. Thus, 3-(inden-2-yl)indoles, derived from an aura-Nazarov cyclization (instead of an aura-iso-Nazarov cyclization), were obtained in moderate to good yields from a variety of 3-propargylindoles | en |
| dc.description.sponsorship | MICINN (CTQ2010-15358 and CTQ2009-09949), Junta de Castilla y Leon (BU021A09 and GR-172), MEC (FPU predoctoral fellowship to D.M.), Ramón y Cajal (contract to M.A F R.), Juan de la Cierva (contract to P.G.G.) | |
| dc.format.mimetype | application/pdf | |
| dc.language.iso | eng | es |
| dc.publisher | Beilstein-Institut | en |
| dc.relation.ispartof | Beilstein Journal of Organic Chemistry. 2011, v. 7, p. 786–793 | en |
| dc.relation.ispartofseries | Gold catalysis for organic synthesis | |
| dc.rights | Attribution 4.0 International | |
| dc.rights.uri | http://creativecommons.org/licenses/by/4.0/ | |
| dc.subject | catalysis | en |
| dc.subject | gold | en |
| dc.subject | indoles | en |
| dc.subject | Nazarov cyclizations | en |
| dc.subject | selectivity | en |
| dc.subject.other | Química orgánica | es |
| dc.subject.other | Chemistry, Organic | en |
| dc.title | Solvent- and ligand-induced switch of selectivity in gold(I)-catalyzed tandem reactions of 3-propargylindoles | en |
| dc.type | info:eu-repo/semantics/article | |
| dc.rights.holder | Este documento está sujeto a una licencia de uso Creative Commons, por la cual está permitido hacer copia, distribuir, comunicar públicamente, remezclar, transformar y crear a partir del material para cualquier finalidad, incluso comercial, siempre que se cite al autor original, se proporcione un enlace a la licencia y se indique si se han realizado cambios | |
| dc.rights.accessRights | info:eu-repo/semantics/openAccess | |
| dc.relation.publisherversion | http://dx.doi.org/10.3762/bjoc.7.89 | |
| dc.identifier.doi | 10.3762/bjoc.7.89 | |
| dc.relation.projectID | info:eu-repo/grantAgreement/MICINN/CTQ2010-15358 | |
| dc.relation.projectID | info:eu-repo/grantAgreement/MICINN/CTQ2009-09949 | |
| dc.relation.projectID | info:eu-repo/grantAgreement/JCyL/BU021A09 | |
| dc.relation.projectID | info:eu-repo/grantAgreement/JCyL/GR-172 | |
| dc.type.hasVersion | info:eu-repo/semantics/publishedVersion | en |
