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dc.contributor.authorÁlvarez Manuel, Estela 
dc.contributor.authorMiguel, Delia 
dc.contributor.authorGarcía García, Patricia
dc.contributor.authorFernández Rodríguez, Manuel A. 
dc.contributor.authorRodríguez, Félix
dc.contributor.authorSanz Díez, Roberto 
dc.date.accessioned2015-07-27T09:55:12Z
dc.date.available2015-07-27T09:55:12Z
dc.date.issued2011-06
dc.identifier.issn1860-5397
dc.identifier.urihttp://hdl.handle.net/10259/3799
dc.description.abstractThe selectivity of our previously described gold-catalyzed tandem reaction, 1,2-indole migration followed by aura-iso-Nazarov cyclization, of 3-propargylindoles bearing (hetero)aromatic substituents at both the propargylic and terminal positions, was reversed by the proper choice of the catalyst and the reaction conditions. Thus, 3-(inden-2-yl)indoles, derived from an aura-Nazarov cyclization (instead of an aura-iso-Nazarov cyclization), were obtained in moderate to good yields from a variety of 3-propargylindolesen
dc.description.sponsorshipMICINN (CTQ2010-15358 and CTQ2009-09949), Junta de Castilla y Leon (BU021A09 and GR-172), MEC (FPU predoctoral fellowship to D.M.), Ramón y Cajal (contract to M.A F R.), Juan de la Cierva (contract to P.G.G.)
dc.format.mimetypeapplication/pdf
dc.language.isoenges
dc.publisherBeilstein-Instituten
dc.relation.ispartofBeilstein Journal of Organic Chemistry. 2011, v. 7, p. 786–793en
dc.relation.ispartofseriesGold catalysis for organic synthesis
dc.rightsAttribution 4.0 International
dc.rights.urihttp://creativecommons.org/licenses/by/4.0/
dc.subjectcatalysisen
dc.subjectgolden
dc.subjectindolesen
dc.subjectNazarov cyclizationsen
dc.subjectselectivityen
dc.subject.otherQuímica orgánicaes
dc.subject.otherChemistry, Organicen
dc.titleSolvent- and ligand-induced switch of selectivity in gold(I)-catalyzed tandem reactions of 3-propargylindolesen
dc.typeinfo:eu-repo/semantics/article
dc.rights.holderEste documento está sujeto a una licencia de uso Creative Commons, por la cual está permitido hacer copia, distribuir, comunicar públicamente, remezclar, transformar y crear a partir del material para cualquier finalidad, incluso comercial, siempre que se cite al autor original, se proporcione un enlace a la licencia y se indique si se han realizado cambios
dc.rights.accessRightsinfo:eu-repo/semantics/openAccess
dc.relation.publisherversionhttp://dx.doi.org/10.3762/bjoc.7.89
dc.identifier.doi10.3762/bjoc.7.89
dc.relation.projectIDinfo:eu-repo/grantAgreement/MICINN/CTQ2010-15358
dc.relation.projectIDinfo:eu-repo/grantAgreement/MICINN/CTQ2009-09949
dc.relation.projectIDinfo:eu-repo/grantAgreement/JCyL/BU021A09
dc.relation.projectIDinfo:eu-repo/grantAgreement/JCyL/GR-172
dc.type.hasVersioninfo:eu-repo/semantics/publishedVersionen


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